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SynTheTic polymers impacT nearly every segmenT of miT engineering profession wiTh applicaTions in commoDiTy anD value aDDeD plasTics anD elasTomers, meDical anD separaTion sysTems, The microelecTronics commerce, anD a hosT of iTems ThaT faciliTaTe energy conversion anD sTorage.RecenT aDvances in polymer chemisTry proviDe economically TracTable TacTics for combining Two or more Types of macromolecules inTo mulTiblock polymers capable of generaTing almosT any imaginable nanoscale sTrucTure enDoweD wiTh remarkable properTies.BuT unforTunaTely, helping The number(D)And opTion(T)Of discrete blocks leads to an explosion in sequencing alternatives, each efficient producing myriad morphologies, similar to the dilemma faced when making new proteins for biological application.As an example, just three sequences are conceivable with n = 3 and k = 3(Mastening numbers, acb in addition to the bac)While n = 4 and k = 3 results in 9 distinct linear blends.A modest improvement in molecular complexity, n = 6 but k = 4, results in 300 unique options!What engineering strategies are around for selecting among the multitude of choices?This lecture outlines the basics underpinning multiblock polymer science and engineering including modern synthetic approaches, how molecular buildings influences structure and properties, fresh characterizations methods, and the present state of predictive statistical theories.Several commercially successful examples will be used to highlight the unparalleled options available for creating new materials and products presented by this emerging class of polymers.

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